RAP opportunity at Naval Research Laboratory NRL
Energy Migration in DNA-organized Dye Networks
Location
Naval Research Laboratory, DC, Electronics Science & Technology Division
opportunity |
location |
|
64.15.25.C0868 |
Washington, DC 203755321 |
Advisers
name |
email |
phone |
|
Paul David Cunningham |
paul.d.cunningham1.civ@us.navy.mil |
202 767 4892 |
Description
The objective of this research effort is to understand the exciton dynamics and energy transfer within dye networks organized by and on DNA scaffolds.
Our work is multidisciplinary. Teams members synthesize dyes (e.g., modified cyanines) as well as DNA sequences and construct dye-labeled DNA origami networks. A wide range of instruments are employed to characterize these materials: chromatography, absorbance, photoluminescence, circular dichroism.
Our group is interested in the delocalization of excitons and energy migrations throughout these dye netoworks. Our research topics include:
- Energy transfer within the FRET and Coherent limits
- Vibronic coupling and exciton delocalization within dye dimers and aggregates
- Suppression of quenching mechanisms
Our Laser Lab is used to interrogate these systems with a variety of static and time-resolved spectroscopic techniques. Our facility includes fluorescence, fluorescence excitation spectra, emission lifetimes via time-correlated single photon counting (TCSPC), femptosecond transient absorption spectroscopy, cryostats compatible with time-resolved setups, etc.
Qualified candidates should possess or be completing a PhD in physics, chemistry, or related discipline with experience in time-resolved spectroscopy. Ultrafast spectroscopy or multidimensional spectroscopy a plus, as is familiarity with photophysics in molecular systems, organic semiconductors, or other excitonic systems.
Recent publications:
Cunningham, et al., J. Phys. Chem. B. 124, 8042 (2020) – doubly excited states in J-dimers
Sohail, et al., Chem Sci 11, 8546 (2020) – 2DES of Vibronic Coherences
Cunningham, et al., Adv. Opt. Mater. 9, 2100884 (2021) – Comparing interacting vs redundant FRET pathways
key words
DNA Origami, FRET, excitons, vibronic, dimers, aggregates, coherence, spectroscopy, time-resolved
Eligibility
Citizenship:
Open to U.S. citizens and permanent residents
Level:
Open to Postdoctoral applicants
Stipend
Base Stipend |
Travel Allotment |
Supplementation |
|
$99,200.00 |
$3,000.00 |
|
|
Additional Benefits
Relocation
Awardees who reside more than 50 miles from their host laboratory and remain on tenure for at least six months are eligible for paid relocation to within the vicinity of their host laboratory.
Health insurance
A group health insurance program is available to awardees and their qualifying dependents in the United States.